Quartz group

Quartz is somewhere on the list of top-five most abundant minerals, and thereby known from scores of deposits, habits, varieties, and associations. We can only point out a few salient features, and encourage you to consult the references below for more comprehensive coverage.
The 'Quartz group' includes minerals composed of silicon dioxide with a couple of close friends with aberrant chemistry. Opal, for example, incorporates water, and Melanophlogite incorporates organic material, that seems to stabilize the crystalline structure - the function of this is not entirely understood. Quartz is an important constituent of most sand, gravel and rocks like granite. Some of the less conspicuous Quartz group minerals occur in volcanic rocks (Cristobalite, Tridymite), sand fused by lightening (Lechatelierite), and meteor impactites (Stishovite and Coesite). Coarse crystalline Quartz is an important component of rocks like granite and pegmatite, and in different varieties such as Rock Crystal, Smoky Quartz, Amethyst, Citrine, and Rose Quartz it is important as lapidary material and specimens.
Cryptocrystalline Quartz, with or without components of hydrated, amorphous silica (see Opal below) are important lapidary materials, including a host of Agates, Chalcedonies, and Jaspers - note, that many stones sold for 'Agate' are not Agate, but some other siliceous rock. Chrysoprase is a vividly green Chalcedony, the fabled 'blue lace Agate' from South Africa is a banded, blue Chalcedony, Tiger-eye is a silicified and altered asbestos rock, etc., etc.
Opal is the main skeletal component of living siliceous sponges and algae (diatoms), and fossil diatoms may form a rock called diatomite. Opal is one of these minerals that happen to be a mineral because of grandfather status - it was known and described before anybody got a clear idea of how to define minerals. The substance we identify as Opal be either hydrated amorphous silica [most text books describe Opal as exactly, and only, that - hydrated amorphous silica], Cristobalite, Tridymite, or a combination of these. The play of colours in precious Opal is due to the morphological organisation of the minerals in small, closely packed spherules [Ramdohr & Strunz (1980), p. 528 has a beautiful picture of this].

Specimen Handling

Quartz group minerals are for all practical purposes stable in a normal household environment. They are not harmed by light, changes in temperature in the normal comfort range, or known to decompose. Quartz group specimens can be fragile and should be handled with care like any other mineral specimen. Quartz group minerals are not appreciably soluble in water. But ... this is a group of minerals, and all sorts of exceptions apply. You may wish to watch out for the following:
Many Quartz crystals, including Amethyst, etc., contain small voids filled with water and gas, as do so-called 'enhydros', Agate geodes enclosing a large cavity filled by air and water. Over time the water may evaporate, leaving just a void. You may believe it is 'sealed in,' but take my word for it, it isn't. Water vapor easily passes through Agate and Quartz. Such specimens may also be susceptible to damage if exposed to high temperatures or sun light. Keep them in the shade, and don't cry when the water is gone.
Some Amethyst and some Rose Quartz is susceptible to fade, when exposed to sun light. The rule of thumb is, all Amethyst fades, but most of it fades slowly, and Rose Quartz coloured due to phosphate (chiefly Rose Quartz crystals and material from a few Brasilian localities) fades rapidly, but Rose Quartz coloured by Rutile does not fade.
Many brightly coloured Agates are dyed, and some dyes fade. Blame that on the processor, not the rock! Some natural colour Agate may fade too, though.
The play of colours in precious Opal is due to the intergrowth of different crystalline and amorphous phases and to water. Consequently, the colours are often lost when the Opal 'dries out', which may be promoted, delayed, or even prevented, depending on storage conditions. Common Opal is subject to the same process, but the visual impact is rarely as profound, though specimens may literally crack.

Bibliography


Anthony, John Williams, Richard A. Bideaux, Kenneth W. Bladh & Monte C. Nichols. 1995. Handbook of mineralogy, vol. 2.2
Bancroft, Peter. 1984. Gem & Crystal Treasures.
Bauer, Max. 1896. Edelsteinkunde, 1st ed.
Bauer, Max. 1909. Edelsteinkunde, 2nd ed.
Bauer, Max. 1968. Precious Stones, I-II. Dover Publications
Bedemar, Vargas. 1822. Der Opal auf den Faröern. Taschenbuch für die gesammte Mineralogie von Karl Cäsar Leonhard. 11-30
Blackburn, William H. & William H. Dennen. 1997. Encyclopedia of mineral names. Canadian Mineralogist, special publication 1.
Dake, H.C., Frank L. Fleener & Ben Hur Wilson. 1938. Quartz Family Minerals
Downing, Paul B.. 1996. African Opal unearthed. After decades of rumors, a recent find may make Ethiopia an important source of Opal. Lapidary Journal. 1996(7), 39-42
Epstein, David Stanley. 1988. Amethyst from Brazil. Gems and Gemology, 24(4), 214-228.
Flörke, Otto W., Heinz G. Mielke, Jürgen Weichert & Holger Kulke. 1981. Quartz with rhombohedral cleavage from Madagascar. American Mineralogist, 66(5-6), 596-600
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Rutland, E.H. 1963. Corundum and amethyst from Tanganyika. Journal of Gemmology, 9(4), 132-135.
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This page is authored by Claus Hedegaard.